Preheat and prepare the pan. Preheat the oven to 350°F. Grease and line the bottom of two 9-inch cake pans with parchment paper. Set aside.
Combine dry ingredients. In a mixing bowl, whisk together flour, sugar, cocoa powder, baking soda, baking powder, and salt.
Combine wet ingredients. In a second mixing bowl whisk together oil, vanilla, eggs, and sour cream.
Add dry ingredients. Using a rubber spatula, stir the dry ingredients into the wet mixture just until incorporated.
Add espresso/hot water. Stir the espresso powder into the boiling water. Carefully stir in the boiling water into the chocolate batter.
Bake. Divide batter between the two pans. Bake 30-35 minutes until the toothpick inserted into the center comes out clean. Remove cake from the oven and allow it to cool for 5 minutes, then turn it out onto a rack to cool completely.