Prep oven and pans. Position a rack in the center of your oven. Pre-heat oven to 350°F (180°C). Grease a 9x13 cake pan with nonstick spray.
Combine dry ingredients. In a large mixing bowl, whisk together the sugar, flour, cocoa, baking powder, baking soda and salt. Set aside. 2 cups (400 g) granulated sugar 2 cups (240 g) all-purpose flour ¾ cup (63 g) Dutch process Cocoa powder 2 teaspoons baking powder 1 teaspoon baking soda ½ teaspoon salt
Combine wet ingredients. In a second large mixing bowl, whisk together the eggs, buttermilk, oil, vanilla extract until well combined. 2 large eggs 1 cup (240 ml) buttermilk ½ cup (120 ml) vegetable oil 2 teaspoons vanilla extract
Combine wet and dry ingredients. Add the wet ingredients to the flour mixture, and stir with a rubber spatula, together just until the last of flour has been incorporated.
Add hot coffee. Stir in the hot coffee to the batter and stir to combine. (batter will be thin). 1 cup (240 ml) hot coffee
Bake cake. Pour batter into the prepared pan. Bake for 40-45 minutes or until a wooden pick inserted in the center comes out clean. Remove the cake from the oven.
Add marshmallows. Sprinkled marshmallows on top of the baked cake in an even layer. Return to the oven for 3-5 minutes until marshmallows are slightly puffed. 10.5 ounce bag of mini marshmallows